Fractionation analysis of transport engine-generated soot particles with respect to hygroscopicity

Combustion-derived particles emitted by various transport engines are analyzed with respect to their morphology and composition. Soot particles collected behind an aircraft gas turbine engine combustor, in the diesel engine exhaust pipe, and at the end of ship pipe demonstrate heterogeneous morphological structures and different chemical identities. Individual particle analysis allows the characterization of emitted soot particles into three fractions, namely C-O, C-O-S, and Fe-C-O, with the dominant presence of chain soot agglomerates, irregular internally mixed soot, and particles of distinct morphology, respectively. The influence of oxygen and sulfur concentrations on the ability of soot to uptake water is proposed as a method for categorizing transport engine-generated particles. Categories of hydrophobic and hydrophilic particles within non-hygroscopic soots can be defined based on the amount of water uptake relative to several reference laboratory-made soots comparable to transport engine emissions. This method of characterizing hydrophobic/hydrophilic and hygroscopic soots in combustion emissions will help to determine the potential impacts of the combustion emissions on CCN/IN formation in the atmosphere.     

Holocene environments and climate in the Mongolian Altai reconstructed from the Hoton-Nur pollen and diatom records: a step towards better understanding climate dynamics in Central Asia

This study presents the results of the palynological and diatom analyses of the sediment core recovered in Hoton-Nur Lake (48°37′18″N, 88°20′45″E, 2083 m) in 2004. Quantitative reconstruction of the Holocene vegetation and climate dynamics in the semiarid Mongolian Altai suggests that boreal woodland replaced the primarily open landscape of northwestern Mongolia at about 10 kyr BP (1 kyr = 1000 cal yr) in response to a noticeable increase in precipitation from 200–250 mm/yr to 450–550 mm/yr. A decline of the forest vegetation and a return to a predominance of open vegetation types occurred after 5 kyr BP when precipitation sums decreased to 250–300 mm/yr. Prior to 11.5 kyr BP diatom concentrations are relatively low and the lake is dominated by planktonic Cyclotella and small Fragilariaceae, suggesting the existence of a relatively deep and oligotrophic/mesotrophic lake. The great abundance of Staurosirella pinnata from the beginning of the record until 10.7 kyr BP might imply intensified erosion processes in the catchment and this is fully consistent with the presence of scarce and dry vegetation and the generally arid climate during this period. From about 10.7 kyr BP, more planktonic diatom taxa appeared and increased in abundance, indicating that the lake became more productive as diatom concentration increased. This change correlates well with the development of boreal woodland in the catchment. Decrease in precipitation and changes in the vegetation towards steppe are reflected by the rapid increase in Aulacoseira distans from about 5 kyr BP. The Holocene pollen and diatom records do not indicate soil and vegetation cover disturbances by the anthropogenic activities, implying that the main transformations of the regional vegetation occurred as a result of the natural climate change. Our reconstruction is in agreement with the paleomonsoon records from China, demonstrating an abrupt strengthening of the summer monsoon at 12 kyr BP and an associated increase in precipitation and in lake levels between 11 and 8 kyr BP, followed by the stepwise attenuation of the monsoon circulation and climate aridization towards the modern level. The records from the neighboring areas of Kazakhstan and Russia, situated west and north of Hoton-Nur, demonstrate spatially and temporally different Holocene vegetation and climate histories, indicating that the Altai Mountains as a climate boundary are of pivotal importance for the Holocene environmental and, possibly, habitation history of Central Asia.     

Late Holocene paleoceanographic evidence of the influence of the Aleutian Low and North Pacific High on circulation in the Seymour-Belize Inlet Complex, British Columbia, Canada

Foraminiferal and thecamoebian faunas from the Seymour-Belize Inlet Complex (SBIC), a fjord network situated on the mainland coast of British Columbia, were studied to assess climatic cycles and trends impacting the area through the AD 850–AD 2002 interval. Ocean circulation patterns prevalent in the SBIC are strongly linked to precipitation, which is closely linked to the relative strength and position (center of action; COA) of the seasonally developed Aleutian Low (AL) and North Pacific High (NPH) atmospheric circulation gyres.Through interpretation of cluster analysis and ordination methods, a period of weak estuarine circulation was recognized to have impacted the SBIC area between AD 850 and AD 1500. During this time waters in the SBIC were dysoxic to anoxic and the sediment–water interface was comprised of a depauperate foraminiferal fauna consisting of low diversity agglutinated forms. These reduced oxygen conditions came about as a result of diminished precipitation in the SBIC catchment as the COA of the AL progressively migrated westward over time, resulting in greatly reduced estuarine circulation and only infrequent and feeble incursions of well oxygenated open ocean water into the SBIC basin. By AD 1575, following a gradual transition period of 75 years when circulation patterns in the inlet were unstable, very strong estuarine circulation developed in the SBIC, concomitant with the onset of the Little Ice Age (LIA) in western Canada. In the SBIC this interval was characterized by higher levels of precipitation, which greatly enhanced estuarine circulation resulting in frequent incursions of cold, well oxygenated ocean currents into the bottom waters of the SBIC and the development of a diverse calcareous foraminiferal fauna. This circulation pattern began to break down in the late 19th century AD and by AD 1940 conditions similar to those that existed in the inlet prior to AD 1500 had redeveloped, a process that continues at present.     

Robotic optical telescopes global network MASTER II. Equipment, structure, algorithms

Presented paper describes the basic principles and features of the implementation of a robotic network of optical telescopes MASTER, designed to study the prompt (simultaneous with gamma radiation) optical emission of gamma-ray bursts and to perform the sky survey to detect unknown objects and transient phenomena. With joint efforts of Sternberg astronomical institute, High altitude astronomical station of the Pulkovo observatory, Ural state university, Irkutsk state university, Blagoveshchensk pedagogical university, the robotic telescopes MASTER?II near Kislovodsk, Yekaterinburg, Irkutsk and Blagoveshchensk were installed and tested. The network spread over the longitudes is greater than 6?h. A further expansion of the network is considered.     

Antipodal effects of lunar basin-forming impacts: Initial 3D simulations and comparisons with observations

3D simulations of basin-scale lunar impacts are carried out to investigate: (a) the origins of strong crustal magnetic fields and unusual terrain observed to occur in regions antipodal to young large basins; and (b) the origin of enhanced magnetic and geochemical anomalies along the northwest periphery of the South Pole-Aitken (SPA) basin. The simulations demonstrate that a basin-forming impact produces a massive, hot, partially ionized cloud of vapor and melt that expands thermally around the Moon, converging near the basin antipode approximately 1 h after the impact for typical impact parameters. In agreement with previous work, analytic calculations of the interaction of this vapor-melt cloud with an initial ambient magnetic field predict a substantial temporary increase in field intensity in the antipodal region. The time of maximum field amplification coincides with a period when impacting ejecta also converge near the antipode. The latter produce antipodal shock stresses within the range of 5-25 GPa where stable shock remanent magnetization (SRM) of lunar soils has been found experimentally to occur. Calculated antipodal ejecta thicknesses are only marginally sufficient to explain the amplitudes of observed magnetic anomalies if mean magnetization intensities are comparable to those produced experimentally. This suggests that pre-existing ejecta materials, which would also contain abundant metallic iron remanence carriers, may be important anomaly sources, a possibility that is consistent with enhanced magnetic anomalies observed peripheral to SPA. The latter anomalies may be produced by amplified secondary ejecta impact shock waves in the thick SPA ejecta mantle occurring near the antipodes of the Imbrium and Serenitatis impacts. Together with converging seismic compressional waves, these antipodal impact shocks may have produced especially deep fracture zones along the northwest edge of SPA near the Imbrium antipode, allowing the ascent of magma with enhanced KREEP concentrations.     

Origin of V. Grib pipe eclogites (Arkhangelsk region,NW Russia): geochemistry,Sm-Nd and Rb-Sr isotopes and relation to regional Precambrian tectonics

Mineralogy and Petrology - In this paper, new main and trace elements and isotopic data are presented for 14 coarse-grained eclogite xenoliths from the V. Grib kimberlite pipe in the central part...     

Estimating masses of selected stars in the Pulkovo program by means of astrometry methods

Stars in the Pulkovo Observatory program are observed with a 65-cm refractor during many years to study their positions and movements. We present examples of two visual binary stars, for which orbits and masses of components were determined, and two astrometric stars, for which masses of their unseen companions were estimated. The first two stars are ADS 14636(61 Cygni) and ADS 7251,and the others are Gliese 623 and ADS 8035(Alpha UMa). Direct astrometric methods are used for estimation of mass-ratio and masses.     

Shock deformation confirms the impact origin for the Cerro do Jarau,Rio Grande do Sul,Brazil, structure

Cerro do Jarau is a conspicuous, circular morpho‐structural feature in Rio Grande do Sul State (Brazil), with a central elevated core in the otherwise flat “Pampas” terrain typical for the border regions between Brazil and Uruguay. The structure has a diameter of approximately 13.5 km. It is centered at 30^o12′S and 56^o32′W and was formed on basaltic flows of the Cretaceous Serra Geral Formation, which is part of the Paraná‐Etendeka Large Igneous Province (LIP), and in sandstones of the Botucatu and Guará formations. The structure was first spotted on aerial photographs in the 1960s. Ever since, its origin has been debated, sometimes in terms of an endogenous (igneous) origin, sometimes as the result of an exogenous (meteorite impact) event. In recent years, a number of studies have been conducted in order to investigate its nature and origin. Although the results have indicated a possible impact origin, no conclusive evidence could be produced. The interpretation of an impact origin was mostly based on the morphological characteristics of the structure; geophysical data; as well as the occurrence of different breccia types; extensive deformation/silicification of the rocks within the structure, in particular the sandstones; and also on the widespread occurrence of low‐pressure deformation features, including some planar fractures (PFs). A detailed optical microscopic analysis of samples collected during a number of field campaigns since 2007 resulted in the disclosure of a large number of quartz grains from sandstone and monomict arenite breccia from the central part of the structure with PFs and feather features (FFs), as well as a number of quartz grains exhibiting planar deformation features (PDFs). While most of these latter grains only carry a single set of PDFs, we have observed several with two sets, and one grain with three sets of PDFs. Consequently, we here propose Cerro do Jarau as the seventh confirmed impact structure in Brazil. Cerro do Jarau, together with Vargeão Dome (Santa Catalina state) and Vista Alegre (Paraná State), is one of very few impact structures on Earth formed in basaltic rocks.     

Influence of subdaily polar motion model on nutation offsets estimated by very long baseline interferometry

This paper studies the connection between the subdaily model for polar motion used in the processing of very long baseline interferometry (VLBI) observations and the estimated nutation offsets. By convention accepted by the International Earth Rotation Service, the subdaily model for polar motion recommended for routine processing of geodetic observations does not contain any daily retrograde terms due to their one-to-one correlation with the nutation. Nevertheless, for a 24-h VLBI solution a part of the signal contained in the polar motion given by the used subdaily model is numerically mistaken for a retrograde daily sidereal signal. This fictitious retrograde daily signal contributes to the estimated nutation, leading to systematic differences between the nutation offsets from VLBI solutions computed with different subdaily polar motion models. We demonstrate this effect using solutions for all suitable 24-h VLBI sessions over a time span of 11 years (2000–2011). By changing the amplitudes of one tidal term in the underlying subdaily model for polar motion and comparing the estimated parameters to the solutions computed with the unchanged subdaily model, the paper shows and explains theoretically the effects produced by the individual subdaily terms on the VLBI nutation estimates.     

Fractal characteristics of the ULF emissions along a meridian profile, based on the 210 MM stations data

Fractal analysis of magnetic records (1 Hz sampling rate) of 5 stations (Guam, Moshiri, Paratunka, Magadan, and Chokurdakh) located along the 210 magnetic meridian (210 MM) has been performed using the Higuchi method. The period of 22 months (October 1992 to July 1994) that embodies the date of the strong Guam earthquake of 8 August1993 has been considered. A comparison of the ULF emissions scaling parameters (spectral exponents β and fractal dimensions D) obtained at different latitudes has been made. Dependence of β and D on the Kp index of geomagnetic activity has been analyzed for each of the 24 local time intervals. It is revealed that D decreases ( β increases) with increasing geomagnetic activity at all stations, but the rates of decrease (increase) are different at different stations and in different time intervals. It is shown that the evening, night and early morning hours are preferable to study magnetospheric effects, whereas the noon hours are the most suitable for the analysis of lithospheric effects. A possibility of using the data of the 210 MM stations as reference materials for the Guam seismically active area is discussed.